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Hazardous or Toxic?
A lesson from the East Palestine, Ohio train derailment
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On February 3rd, 2023, a train carrying hazardous materials derailed near East Palestine, Ohio. The train carried various chemicals, including vinyl chloride, ethylhexyl acrylate, and ethylene glycol monobutyl. The derailment resulted in a fire, and chemical release into the surrounding environment, leading to the evacuation of residents.

The National Transportation Safety Board (NTSB) has launched an investigation into the incident to determine the cause and make recommendations to prevent similar accidents in the future.

One thing I noticed about the news coverage is the language; some call the chemicals hazardous, and some use the word toxic. So, which is it?

Were Hazardous Chemicals or Toxic Chemicals Involved? What's the Difference?

The U.S. government defines hazardous materials under the Hazardous Materials Transportation Act (HMTA) and its corresponding regulations, which the Pipeline and Hazardous Materials Safety Administration (PHMSA), an agency within the U.S. Department of Transportation, oversees.

These regulations broadly define hazardous materials as any substances or materials that pose an unreasonable risk to health, safety, or property when transported in commerce, including toxic, flammable, corrosive, explosive, radioactive, or otherwise dangerous substances.

To be more specific, the regulations list specific classes of hazardous materials based on their physical and chemical properties and potential hazards. These classes include explosives, gases, flammable liquids and solids, oxidizing substances, toxic substances, radioactive materials, corrosive substances, and miscellaneous dangerous goods.

If a substance falls under one of these classifications, it is considered a hazardous material and is subject to strict regulations for safe transportation in commerce. These regulations cover the packaging, labeling, marking, and handling hazardous materials to ensure they are transported safely and without incident.

So what are toxic chemicals? A material is toxic if it is capable of causing harm to human health, such as illness or injury, through ingestion, inhalation, or skin contact. Toxicity can be acute or chronic, and the degree of harm can depend on several factors, including the material's concentration, the exposure length, and the susceptibility of the exposed individual.

The Environmental Protection Agency (EPA) has also established a list of hazardous air pollutants (HAPs), including chemicals known or suspected to cause cancer, birth defects, or other serious health effects. HAPs are regulated under the Clean Air Act, and their emissions are subject to strict controls to protect human health and the environment.

As you can see, toxic is a category of hazardous materials. So, when you use the term "Hazardous Chemical," you may be referring to any of the categories listed under regulations, making it a generic label. But when you say "Toxic Chemicals," you refer to a specific hazardous chemical type.

All toxic chemicals are hazardous, but not all hazardous chemicals are toxic. You get the point - Blaine J. Hoffmann, MS OSHM

Chemicals Involved 

There were reportedly several chemicals of concern involved in the train derailment.

Vinyl chloride is a colorless gas that produces polyvinyl chloride (PVC), a widely used plastic material. It is also an intermediate in making other chemicals, such as chlorinated solvents and pharmaceuticals.

Exposure to vinyl chloride can harm human health, and it is considered a toxic and carcinogenic substance, meaning it can cause cancer. Inhalation of vinyl chloride can irritate the respiratory system and cause dizziness, headaches, and fatigue. Long-term exposure to high levels of vinyl chloride has been linked to an increased risk of certain types of cancer, including liver cancer and angiosarcoma (rare cancer affecting the blood vessels).

Due to the health risks associated with vinyl chloride, it is strictly regulated by government agencies such as the Occupational Safety and Health Administration (OSHA) and the Environmental Protection Agency (EPA). These agencies have established exposure limits and other requirements to protect workers and the public from the harmful effects of vinyl chloride.

Ethylhexyl acrylate is a chemical compound belonging to the acrylic esters group. It is a clear, colorless liquid with a slightly pungent odor. It is used as a monomer in producing various polymers, including acrylic and copolymers.

Ethylhexyl acrylate is primarily used as a building block in synthesizing polymer-based products, such as adhesives, coatings, and elastomers. It is also a surfactant and an intermediate in producing other chemicals.

Exposure to ethylhexyl acrylate can irritate the eyes, skin, and respiratory tract, causing headaches and dizziness. It may also cause allergic reactions in some individuals. The International Agency for Research on Cancer (IARC) has classified ethylhexyl acrylate as a Group 2B carcinogen, which means it is possibly carcinogenic to humans based on animal studies. However, more research is needed to understand this substance's potential health effects fully.

 

Government agencies, such as the Occupational Safety and Health Administration (OSHA) and the Environmental Protection Agency (EPA), regulate ethylhexyl acrylate to protect workers and the public from potential health risks. These agencies have established exposure limits and other requirements for safely handling and using this substance.

Ethylene glycol monobutyl, or 2-butoxyethanol, is a clear, colorless liquid with a mild, sweet odor. It is a glycol ether used primarily as a solvent in various industrial and commercial applications.

Ethylene glycol monobutyl is used as a solvent in producing resins, lacquers, and other coatings. It is also used as a cleaning agent and in making various types of chemicals, including plasticizers, textile dyes, and pharmaceuticals.

Exposure to ethylene glycol monobutyl can irritate the eyes, skin, and respiratory tract and cause headaches, nausea, and dizziness. Long-term exposure to high levels of this substance can cause damage to the liver, kidneys, and blood cells. In addition, ethylene glycol monobutyl has been associated with developmental and reproductive effects in laboratory animals.

Government agencies, such as the Occupational Safety and Health Administration (OSHA) and the Environmental Protection Agency (EPA), regulate ethylene glycol monobutyl to protect workers and the public from potential health risks. These agencies have established exposure limits and other requirements for safely handling and using this substance.

Exposure limits to chemicals set by the government do not necessarily mean that there will be no harm, as the toxicity of chemicals can depend on various factors, including the level of exposure, the duration of exposure, and the individual's susceptibility to the effects of the chemical. These limits are designed to minimize the risk of adverse health effects to workers, consumers, and the general public - not eliminate the risks.

It is important to note that exposure to levels below the set limits may still cause adverse health effects, particularly for individuals more susceptible to the effects of the chemical, such as children, pregnant women, and people with pre-existing medical conditions.

Therefore, it is crucial to follow safety guidelines and precautions when working with or around hazardous chemicals, including using appropriate protective equipment, ensuring proper ventilation, and following safe handling and disposal procedures. It is also critical to seek medical attention if you observe any symptoms of exposure to chemicals.

What about risks due to mixing or by-products?

These chemicals could form hazardous by-products if accidentally mixed, combined, or burned.

For example, mixing vinyl chloride with ethylhexyl acrylate could form a polymer, which can release toxic fumes and cause respiratory irritation. Mixing vinyl chloride with ethylene glycol monobutyl could lead to the formation of other harmful compounds, including aldehydes and ketones, which can irritate the eyes, nose, and throat, as well as cause headaches and dizziness.

The exact by-products of combining these chemicals would depend on the specific conditions of the reaction, such as the amount of each chemical present, the temperature, and the presence of other reactive compounds. Handling, separately handling, and transporting these chemicals is essential to avoid accidental mixing and potential harm to human health and the environment. For example, if transporting these chemicals on the same train, you would want other train cars with inert materials, or even empty ones if possible, separating them in the event of an accident, like a derailment.

In addition to Vinyl chloride, ethylhexyl acrylate, and ethylene glycol monobutyl being hazardous chemicals in and of themselves, burning them can produce a variety of potentially hazardous by-products, including:

  1. Carbon monoxide and carbon dioxide: These are typical by-products of the combustion of most hydrocarbons and can contribute to local air quality issues.
  2. Hydrogen chloride: This corrosive gas can cause respiratory and skin irritation and contribute to acid rain.
  3. Dioxins and furans are highly toxic compounds produced when organic matter, such as plastics, is burned. They can cause various health effects, including cancer, reproductive and developmental problems, and immune system damage.
  4. Acrolein is a highly reactive and irritating gas that can cause respiratory and eye irritation and contribute to air pollution.
  5. Soot and particulate matter: These tiny particles can be released during combustion and contribute to air pollution and respiratory problems.

It is important to note that the by-products of burning these chemicals can vary depending on various factors, such as the temperature and duration of the burn, the presence of other substances, and the conditions of the combustion process. Therefore, taking appropriate precautions when handling, transporting, and disposing of these chemicals is essential to minimize the risk of harm to human health and the environment.

What about the environmental impact? 

The Ohio Environmental Protection Agency received results from their water sampling of the five wells that feed into East Palestine's municipal water system. The results show no detection of contaminants associated with the derailment. The Ohio EPA said they are confident that the municipal water is safe to drink and have said steel casing protects the wells from contamination.

The Ohio EPA also recommends that residents with private wells schedule an appointment for well water testing by an independent consultant. The Ohio Department of Health encourages those with private wells to use bottled water until their well water testing results come back.

What about the Ohio River impact? Tiffani Kavalec, chief of the Division of Surface Water at the Ohio Environmental Protection Agency, said the chemicals spilled into the Ohio River. Still, since it is such an enormous body of water, it can dilute the chemicals quickly.

However, during a press conference, Ohio Department of Natural Resources director Mary Mertz said four tributaries over a space of 7.5 miles along the Ohio River are contaminated. Still, officials are confident those waterways are contained and do not affect municipal water supplies. Nevertheless, the contaminated waterways have led to the deaths of some 3,500 fish. According to Mertz, none of the 12 species of dead fish are threatened or endangered, and there was no impact on nonaquatic life.

The 111 water samples collected from the day of the derailment through February 14th, 2023, were tested for butyl acrylate, vinyl chloride, ethylene glycol monobutyl ether, and ethylhexyl acrylateno. The result showed no detectable levels of the chemicals.

The public perception of this being a more significant threat than authorities indicate stems from people seeing a plume or sheen on the water in the Ohio River. A visible plume on the water may indicate detectable levels of harmful chemicals, but it is not a reliable indicator.

Some chemicals can be harmful in small concentrations, while others may not pose a significant risk, even at high concentrations. The appearance of a plume can depend on various factors, such as the type of chemical, the quantity and duration of the release, and the characteristics of the water body.

To determine if there are detectable levels of harmful chemicals in the water, appropriate testing and analysis of water samples must occur, which can involve using specialized equipment to measure the concentration of specific chemicals or perform a broader screening of the water for a range of potential contaminants.

It is important to note that even if detectable levels of harmful chemicals are in the water, this does not necessarily mean that there is an immediate health risk. The risk to human health and the environment will depend on various factors, such as the toxicity and quantity of the chemical, the exposure pathway, and the population's sensitivity.

Conclusion

This article used a recent disaster to illustrate how the media, even as safety professionals, can create confusion and panic by using the wrong words to describe events and substances involved.

To be clear, this train derailment is a tragedy. Full stop. At the time of this publishing, the long-term impact of this tragedy is unclear. Regardless, the emotional impact is clear; residents have lost confidence in the local, state, and federal agencies and the rail carrier due to their response and various communications failures. What do you think? Be sure to leave your comments below.


Drew Hinton, Ph.D., CSP, CHMM, EMT
Drew Hinton, Ph.D., CSP, CHMM, EMT

Drew Hinton is President/CEO of Arrow Safety and has 10 years of experience as a career Firefighter/EMT/HazMat Officer in Louisville (KY) and 15 years as a safety professional.

 

Blaine J. Hoffmann, MS OSHM
Blaine J. Hoffmann, MS OSHM

Blaine J. Hoffmann has been in the occupational safety & health industry for over 27 years. He is the producer and host of The SafetyPro Podcast and founded the SafetyPro Podcast Community Site.

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Protesting and Demonstrating Safely
What Safety Professionals Need to Know

Introduction: Why This Matters Now

In today's tense social and political climate, workers across all industries are increasingly finding themselves involved in or near public protests. These events may be rooted in calls for justice, policy changes, or labor rights, but they can also occur quickly, with little warning, and sometimes escalate into unsafe situations. As safety professionals, we often find ourselves offering support for off-the-job safety and, in this case, understanding the realities of public demonstrations, protests, and the legal and physical boundaries that accompany them.

With news cycles spinning at full speed and emotions often running high, many workers have legitimate questions about their rights and responsibilities. Can they protest? Where? What happens if the situation turns volatile? More importantly, how can safety professionals engage in clear, respectful, and legally informed conversations with workers to help them protect themselves without discouraging their civil participation?

To do this, we must first provide the necessary context for understanding the First Amendment's protections, clarify common misconceptions, and give you practical talking points to help your teams navigate these complex situations.

What the First Amendment Protects—and What It Doesn't

The First Amendment of the U.S. Constitution protects the right of individuals to peaceably assemble, which means they can gather in public to express their views without fear of government retaliation, as long as the assembly is nonviolent. This right typically applies to traditional public forums such as sidewalks, parks, streets, and public plazas. However, the government can impose reasonable restrictions on the time, place, and manner of protests as long as those rules are content-neutral, serve a legitimate public interest (such as safety or order), and leave open alternative channels for expression. For example, cities may require protest permits to ensure public safety and traffic flow, and it is legal for them to do so.

This constitutional protection does not extend to violent gatherings, riots, or demonstrations that damage property or obstruct critical public functions. Protesters do not have the right to block streets, traffic, or access to government buildings unless local authorities permit such actions. Likewise, they cannot protest on private property without the owner's consent. Participation in unlawful activity—even within a larger peaceful protest—can result in arrest or other legal consequences.

Several key Supreme Court cases clarify these boundaries. In Cox v. Louisiana (1965), the Court upheld restrictions against protests that block public access to government functions. To quote from the decision:

"The constitutional guarantee of liberty implies the existence of an organized society maintaining public order, without which liberty itself would be lost in the excesses of anarchy. The control of travel on the streets is a clear example of governmental responsibility to insure this necessary order. One would not be justified in ignoring the familiar red light because this was thought to be a means of social protest. Nor could one, contrary to traffic regulations, insist upon a street meeting in the middle of Times Square at the rush hour as a form of freedom of speech or assembly. Governmental authorities have the duty and responsibility to keep their streets open and available for movement. A group of demonstrators could not insist upon the right to cordon off street, or entrance to a public or private building, and allow no one to pass who did not agree to listen to their exhortations."

In Clark v. Community for Creative Non-Violence(1984), the Court supported limits on protest locations when the rules were content-neutral and preserved the public's use of the space. In 1982, the National Park Service issued a permit to Community for Creative Non-Violence (CCNV) to conduct a demonstration in Lafayette Park and the Mall, which are National Parks in the heart of Washington, D.C. However, the Park Service, relying on its regulations, particularly one that permits "camping" (defined as including sleeping activities) only in designated campgrounds, no campgrounds having ever been designated in Lafayette Park or the Mall, denied CCNV's request that demonstrators be permitted to sleep in the symbolic tents.

The regulation forbidding sleeping meets the requirements for a reasonable time, place, or manner restriction of expression, whether oral, written, or symbolized by conduct. The regulation is neutral regarding the message presented and leaves open ample alternative methods of communicating the intended message.

Ward v. Rock Against Racism (1989) further affirmed that time, place, and manner restrictions are valid if they are narrowly tailored and do not target the content of the protest. Rock Against Racism was a performance group seeking to use the bandshell pavilion for a concert. New York City imposed regulations on the use of the bandshell in Central Park, seeking to control the sound volume of concerts there. The City provided sound amplification equipment and a sound technician for the performers to use, and they were required to use them. There was no substantial burden here since the concerts could continue with adequate equipment, and the restriction was content-neutral. It was justifiable for the City to prevent the sound from interfering with people in quieter surrounding areas.

Meanwhile, Adderley v. Florida (1966) clarified that the government can prohibit protests on certain public properties—like jails or military installations—that are not traditionally open to the public. A group of students was protesting on a nonpublic jail driveway, which they blocked to demonstrate against their schoolmates' arrest. The sheriff advised them that they were trespassing on county property and would have to leave or be arrested. The demonstrators refusing to leave were then arrested and convicted under a Florida trespass statute. The protestors claimed that their convictions deprived them of their "rights of free speech, assembly, petition, due process of law, and equal protection under the laws" under the Fourteenth Amendment. The Judges found that there was ample evidence to support the protestors' trespass convictions for remaining on jail grounds reserved for jail uses after they had been directed to leave by the sheriff. There was no evidence that protestors were arrested or convicted for their views or objectives. Furthermore, they affirmed:

"The rights of free speech and assembly, while fundamental in our democratic society, still do not mean that everyone with opinions or beliefs to express may address a group at any public place and at any time. The constitutional guarantee of liberty implies the existence of an organized society maintaining public order, without which liberty itself would be lost in the excesses of anarchy. . . . A group of demonstrators could not insist upon the right to cordon off a street, or entrance to a public or private building, and allow no one to pass who did not agree to listen to their exhortations."

Putting it into Practice

For safety professionals, it's critical to understand and communicate this balance. Workers should be encouraged to express themselves lawfully and peacefully. Still, they must also understand the limits of their rights and the potential legal and safety risks associated with their actions. Participating in protests on public sidewalks or in designated areas is typically lawful, provided they do not block traffic or access to buildings. Remember, the general public has a right to freedom of movement that the police will protect.

Disorderly conduct is the most frequently cited violation that can land a protester in legal trouble. Here are just a few examples of unprotected disorderly conduct that might arise at a protest:

  • Blocking/preventing access to abuilding
  • Disrupting normal official business/operations
  • Harassing someone by blocking their free movement in a public way, such as roads and sidewalks
  • Forcing the public to listen to an unwanted message (not letting people pass)
  • Fighting words
  • Making noise in a residential neighborhood in violation of local ordinacnes
  • Disrupting a government hearing by standing and shouting in the hearing room

It's also important to respect local laws and ordinances, including any curfews or permit requirements that may apply. Workers should be reminded that their actions during protests can have personal and professional consequences, especially if they engage in illegal conduct or violate employer policies, such as participating while wearing company uniforms or during paid work hours.

A practical way to convey this message might be:

"We fully support everyone's constitutional rights, including the right to peaceably assemble. If you choose to protest, please do so safely and lawfully. Stay in public areas that are open to assembly, avoid blocking streets or entrances to public buildings, and follow lawful police instructions. Your voice matters—and so does your safety."

Helping workers understand these nuances allows safety professionals to maintain a respectful, informed, and safety-focused dialogue during turbulent times, protecting both individual rights and worker safety. Remember:

  • Blocking Entrances and Traffic: Protesters can be arrested for blocking building entrances or obstructing pedestrian and vehicle traffic, as these actions directly interfere with the public's right to use public spaces. Interference with government functions can be a federal offense, which includes obstruction with the intent to disrupt or impede government business.
  • Permit Requirements: For larger demonstrations that may require street closures or special accommodations, obtaining a permit is a common requirement to help manage traffic and logistics without preventing the protest itself.
  • Noise Regulations: The government can regulate the use of sound amplification devices to prevent excessive noise that would disrupt normal operations.

Conclusion: Leading with Clarity and Compassion

Protests are not new, but the way we engage with them as professionals must evolve. Whether due to social media influence, lack of civics education, or local officials tolerating illegal behavior, many protests today can easily violate the law. The First Amendment is often invoked to justify forcing others to listen to a message, restricting their freedom of movement, or even destroying property - this is not protected speech. More often than not, the speech (the overall message) is not the issue; rather, it is an issue with the right to peaceable assembly, a part of the First Amendment that is often overlooked or misinterpreted.

Whether your team members are directly participating in demonstrations or may encounter them during work-related travel or commuting, you need to provide clear guidance that respects both their rights and their safety. As a safety leader, your credibility rests not just on knowing the law but on being able to translate that knowledge into calm, practical advice during moments of uncertainty.

Encourage lawful, peaceful participation where appropriate. Make sure your workers understand where those boundaries lie—and where the risks begin. Most of all, create an environment where they feel comfortable coming to you with questions, knowing that your goal is not to control or stifle but to support and protect.

Helping people stay safe sometimes means knowing when to step back and when to speak up. Let’s make sure they’re equipped to do both.


Blaine J. Hoffmann, MS OSHM
Blaine J. Hoffmann, MS OSHM

Blaine J. Hoffmann, MS OSHM, has been in the occupational safety & health industry for over 28 years and is the author of Rethinking SAFETY Culture and Rethinking SAFETY Communications. Blaine is the producer and host of The SafetyPro Podcast and founded the SafetyPro Podcast community site.

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The Leadership Shadow
Leading by Example - Leaders Eat Last

Summary of Key Point:

People don’t follow words; they follow actions. A leader’s behavior creates the foundation of the team’s culture. If you expect accountability, trust, and excellence, you must embody those values yourself. By consistently demonstrating the behaviors you want to see, you establish trust and set clear expectations without relying solely on directives or policies.

Application in Your Life:

Leadership by example means embracing the habits and attitudes you wish to see in others. For example, if you want your team to prioritize safety, ensure you’re always following safety protocols yourself—even when it’s inconvenient. If you value open communication, regularly share your own thoughts and listen actively when others speak. Over time, your actions become a benchmark for the team, shaping their daily decisions and attitudes.

Reflection Points:

  1. How closely do my actions align with the values I talk about?
  2. Are there instances where I’ve sent mixed signals through my behavior?
  3. What’s one small change I can make today to better model the values I expect from my team?

Teaching Approach:

  • Explain the Concept: Use the “parent-child” analogy—children watch their parents’ actions more closely than they listen to their words. In the same way, team members internalize the behavior their leader demonstrates.
  • Activity: Ask participants to identify a specific behavior or value they want their team to adopt, such as punctuality, attention to detail, or respectful communication. Then have them outline one practical way they will consistently model that behavior in their daily work.
  • Follow-Up: Encourage participants to track their efforts for a week and note any changes in their team’s behavior, sharing observations in the next meeting. This can lead to a group discussion on what worked, what was challenging, and how modeling behaviors can create lasting cultural shifts.
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Daily Leadership Topic: The Johari Window
Building Self-Awareness Through Feedback

Summary of Topic:
The Johari Window is a tool that helps individuals understand themselves better through feedback and self-disclosure. It’s divided into four quadrants:

  1. Open Area (known to self and others) – What you’re aware of and others see too.
  2. Hidden Area (known to self but not others) – What you choose not to share.
  3. Blind Spot (not known to self but known to others) – What others see but you don’t realize.
  4. Unknown Area (not known to self or others) – What hasn’t yet been discovered.

The goal is to expand the Open Area by giving and receiving feedback, fostering trust, and promoting personal growth.

Application in Your Life:
Identify a trusted colleague or mentor and ask for constructive feedback. Start by sharing something about yourself (reduce the Hidden Area) and ask for insights into how you’re perceived (reduce the Blind Spot). Over time, this transparency improves communication and strengthens relationships.

Reflection Points:

  1. What’s one piece of feedback I’ve received that helped me see my blind spots?
  2. How can I create a safe environment for open feedback with my team?
  3. What steps can I take to increase the Open Area and improve my self-awareness?

Teaching Approach:

  • Explain the Concept: Use a simple analogy—like cleaning a foggy mirror, honest feedback helps us see ourselves more clearly.
  • Activity: Have participants pair up and share one strength they feel confident about and one area they’d like feedback on. Then, discuss how the Johari Window helps them expand their Open Area.
  • Follow-Up: Encourage them to seek feedback regularly and track how it impacts self-awareness and performance over time.
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